Hexa-substituted polyoxometalates made of trivacant Dawson {P2W15} fragments and {Ni6} clusters under hydrothermal conditions.

نویسندگان

  • Yong-Chao Liu
  • Chun-Hua Fu
  • Shou-Tian Zheng
  • Jun-Wei Zhao
  • Guo-Yu Yang
چکیده

Three novel polyoxometalates (POMs) containing [Ni6(μ3-OH)3](9-) and [P2W15O56](12-) units were first made, showing the first hexa-nuclearity transition-metal substituted POMs (TMSPs) based on monomeric lacunary Dawson fragments, which further indicates that the hydrothermal technique can offer an effective way for making new TMSPs through lacunary POM fragments incorporated with high-nuclear TM clusters.

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عنوان ژورنال:
  • Dalton transactions

دوره 42 48  شماره 

صفحات  -

تاریخ انتشار 2013